Except where otherwise noted, data are given for materials in their (at 25 °C 77 °F, 100 kPa).Y ( Y N?)Dimethylglyoxime is a described by the formula CH 3C(NOH)C(NOH)CH 3. Its abbreviation is dmgH 2 for neutral form, and dmgH for anionic form, where H stands for hydrogen. This colourless solid is the di derivative of the diketone butane-2,3-dione (also known as ).
DmgH 2 is used in the analysis of. Its are of theoretical interest as models for enzymes and as catalysts. Many related ligands can be prepared from other diketones, e.g.Preparation Dimethylglyoxime can be prepared from first by reaction with to give.
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The second is installed using sodium monosulfonate:Complexes Dimethylglyoxime is used to detect and quantify, which forms the bright red complex (Ni(dmgH) 2). The reaction was discovered by in 1905.Cobalt complexes have also received much attention. In the macrocycle dmgH 2 2− mimics the macrocyclic ligand found in.